"The president is constitutionally bound to inform Congress prior to any military action."
EDIT:
Sorry this is completely wrong. That is the president acting as Commander in Chief. What would be more proper is that he is constitutionally bound:
"to enforce the acts of Congress, the judgements of federal courts, and treaties signed by the United States."
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There are different titles for the chief executive. In some countries the chief executive is call president. In many companies, he or she is called the chief executive or chief executive officer.
The president is chief of the executive branch of government.
The US Government Chief Executive is the President.
The President is chief executive of the Executive Branch of the US government.
One of the most important duties of the president is to serve as the chief executive or chief administrative officer of all government agencies. As such he is the chief executive of the nation.