Yes, the U. S. President appoints ambassadors. His/Her appointments must be approved by Congress.
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The President of the United States has the power to appoint many different offices. These include federal judges, ambassadors, cabinet officers, and military leaders.
Franklin D. Roosevelt
The Senate (legislative branch) must confirm (approve) these appointments by the President. Thus the power to appoint is divided
The President appoints new supreme court justices.
The president has the power to nominate or appoint judges, ambassadors, cabinet members and other high ranking officials., subject to approval or confirmation by the US Senate.