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The main purpose of the Executive Office of the President is to help the President carry out his or her duties as chief executive.
the powers of the legislative branch is to make the law for the nation *
The main duties of the president are to carry out the laws, oversee the agencies of government, negotiate with foreign governments, issue pardons, and perhaps most important be commander in chief of the armed forces.
The duties of the Vice President is to support the President's agenda, they are in charge of the Senate, so if they have to opportunity to get in there with the senators and make some good policy changes. The also cast a tie breaking vote in the Senate. Also if something were to happen to the President, they are the one that would replace him.
The twenty-fifth Amendment in the only one related to presidential succession. It allows the Vice President to take office, and allows the President to temporarily give up his powers, and later retake them, and allows the Vice President and Cabinet to collectively temporarily remove the President.Article 2, section 1 clause 6 . of the main body of the Constitution allows the Vice President to take the duties of the President, but does not explicitly make him the President. This same clause gives Congress the power to establish this order of succession but does not specify the order beyond vice president. Accordingly Congress passed a law (Title 3 of the United States Code, section 19) which specifies an order of succession for the cases where the President and Vice President are both unable to serve. See the related question for this order.