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Constitutional law is mainly concerned with the structure of the primary organs of government. Constitutional law is also concerned with the fundamental principles according to which a state or organization is governed.
Assuming that the federal law can be said to have a reasonable connection to the Article I, Section 8 Powers given to Congress, the federal law will supersede the state law and render the state law non-operative. If the federal law is not said to have a reasonable connection to the Article I, Section 8 Powers, it is rendered unconstitutional and the state law prevails.
The Constitution.
A major exception is the public policy exception. Federal courts are less likely to force a state to enforce the laws of a second state where that law conflicts with the public policy of the first state.
The Supreme Court declare state law unconstitutional