The Vice-President is part of the Executive branch of the US government, but he is also President of the Senate, which carries very little power (may break tie votes).
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The President of the United States is the head of the Executive Branch of the Federal Government.
the president
The legislative branch selects the head of government - Apex
The Judicial Branch, or the federal court system, interprets the law. The US Supreme Court, head of the Judicial Branch, is the ultimate authority on the interpretation of federal law and the constitutionality of any law.
The US President is head of the Executive branch of the federal government. The President's cabinet (advisors, department heads and all their employees) also belong to this branch.