The chief executive of anything, whether political or private is the person who is in charge of everything. It can be a role as well as a title or position. It usually means that person has final say over everything.
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The President is the chief executive officer.
There are different titles for the chief executive. In some countries the chief executive is call president. In many companies, he or she is called the chief executive or chief executive officer.
The US Government Chief Executive is the President.
The President is chief executive of the Executive Branch of the US government.
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