Deputy to the Governor or deputy governor Deputy to the Governor or deputy governor Deputy to the Governor or deputy governor
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The 2nd in command of any naval vessel or command is known as the Executive Officer, or XO for short. In the Army and Marines, it's typically the Chief of Staff or something similar, but XO is also used. Rank doesn't make any difference - the title is given to whoever is the Commanding Officer's 2nd under him. This is true for both ships and shore installations.
Governor
state government federal government
Justin cartrette the secretary of state dose
Most of them hold the title of Secretary of whatever department they head, Secretary of State being an example. The Attorney General heads the justice department. In years past, the Postmaster General was a cabinet member. The usual form of address is "Mr. (or Madame) Secretary", if that's what you were asking.