Dred Scott v. Sanford, 60 US 393 (1857)
The court case was Dred Scott v. Sandford, in 1857.
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The Supreme Court gained the power to declare laws unconstitutional
It was only unconstitutional if you accepted Roger Taney's interpretation of the Constitution in his judgment of the Dred Scott case in 1857. He said the Constitution protected slavery - so therefore no state could declare itself to be free soil.
declare a law unconstitutional
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The Supreme Court declare state law unconstitutional