In the absence of the Vice President then the Speaker of the House would next in line for the presidential line of succession. Then it would go to president pro tempore of the senate and then secretary of state.
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The Vice President
president-protempore
(In the U.S) The President Pro Tempore usually acts as president of the senate. Currently, this is Daniel Inouye.
The US Vice President performs the duty as the President of the Senate. He or she has no vote except in situations where there is a tie in votes. The Vice President is then allowed to vote to settle the issue at hand.
The President pro tempore (Latin for "president for a time") typically presides in the Vice President's absence. The most senior senator of the majority party is customarily chosen to serve in this position. Like the Vice President, the President pro tempore does not normally preside over the Senate, but typically delegates the responsibility of presiding to junior senators of the majority party.