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The Aztec Empire was located in what is today known as Mexico. Its capital, Tenochtitlan, was destroyed and rebuilt as Mexico City.
The Empire of Ethiopia ( today Ethiopia ) was the country once known as Abyssinia.
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The Chaldeans leaved around 600 BC in the south of an area known as Babylonia. This area today is part of Syria. The area known as Chaldea was absorbed into the Persian empire.
It was founded by Cyrus the Great and reached its peak under Darius the Great. However it was not the largest ever known - compare it with the Spanish Empire, the British Empire and the Russian Empire.