Hepheastus and Ares are the more known children that she had but she also had:
Eris, Hebe, Eileithyia,
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Yes, Zeus had demigods he hasn't in a while because he married Hera.
Leo is what the Constellation of the Lion is called; it was once the Nemean Lion whom Heracles defeated and Hera put into the stars. It had no offspring, demigod or not.
Yes, Hercules.
Yes. a few are Theseus,Polyphemus(cyclops),Neleus,Orion,etc. Other than Polyphemus the rest of them are demigods. These are just a few of his childern, not all.
hera threw him off stuff