Yes, I cannot recall his name but Heracules did have a brother. When Zeus had an affair with another mortal Hera with furious. This lead her to send Heracules into a fit of insanity making him kill his own brother. Later Heracules completed the twelve labors to become immortal. Then he took his rightful place on Mount Olympus with Zeus.
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He had four sons by Deianeira. Sometimes 6 other children are mentioned.
Procris - Antileon & Hippeus
Panope - Threpsippas
Lyse - Eumedes
? - Creon
Epilais - Astyanax
Theseus doesn't have any full brothers. But if you believe that he is the son of Poseidon, then all of Poseidon's sons would be his half-brothers.
Hercules and Hermes are both sons of Zeus. They are half brothers.
Alcmene with Zeus had Hercules, his twin brother was Iphicles. The sisters of Hercules included Laonome and Perimede.
Zeus is the father of Hercules. Zeus had over 100+ children, so therefore Hercules had a bunch of half brothers and sisters.
Hercules didn't have a brother or a sister but because he was the son of Zeus, he had many half brothers and sisters including Apollo,Artemis,Athena,Persephone and many more( they were all offsprings of Zeus)
Aphrodite is her half sister. Hercules and Poros are her half brothers.