Artemis, she was the goddess of hunting.
It is also Orion which is the God of Hunting in Greek Mythology.
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He was a god. No. Orion was the great-hunter hero of a culture that probably pre-dated the Greek and got absorbed into the Classical Greek mythology. He was killed either by the bow of Artemis or from a sting from a scorpion.
Zeus was not a Greek Hero, but was the King of the Greek Gods. He father was the Titan, Cronus.
Hercules is a Greek hero. -- The Greek hero was called Heracles. Hercules is simply his Latin (Roman) name.
Dionysus, the Greek god of festivals, in the writings of Euripides can be considered the first anti-hero.
I think the greatest mythological greek hero would be Hercules because he did 12 almost impossible tasks.