Begining of the metal age
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The neolithic era was famous for the beginning of human technology. The neolithic era is known as the end of the stone age. You can get more information about the neolithic era online at the Wikipedia.
The Neolithic Revolution ended in about 600 C.E., when people started settling down and empires started developing.
The surrender of the beseiged city of Athens to the the Peloponnesian land and naval forces led by Sparta.
The Age of Contentment..... Well no one really knows why it did end but there is a myth of Prometheus the Fire-Bringer that does give you an idea of why it ended.