No millions of years before humans wasps were producing a paper like substance to build their nests. Which of course they still do.
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In Egypt
I think it was the Egyptians - papyrus is paper made out of reeds...
Papyrus is paper invented in 3000bc and was used for paintings and writing until the 11th century AD.
in the ancient Egyptian era
The Egyptian invented the papayrus from a certain plant, from which we get the word paper.