Edith Hamilton's Mythology is a collection of myths and stories, therefore there is no one main character.
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Tales told by word of mouth and collected into the mythology of a ancient people who thought of it as a religion do not often come with titles. They are now known by the main characters.
The main god of Greek mythology would be Zeus, the king of the gods. for he is ruler of heaven and earth. he is also king of the world.
To explain mysteries of nature.
Odysseus was the main character of the Odyssey.
There are many gods in Greek mythology, but the main ones are the 12 Olympian gods who ruled from Mount Olympus.