They are the daughters of Ares and Hespires. They look after Hera's golden apples, but gave some to Atlas to give to Heracles for one of his Twelve Labours.
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Hesperides
The golden apples of the Hesperides.
Atlas's daughters were Hesperides, Hyades, Hyas, Pleiades, Calypso, Dione and Maera.
The eleventh labour of Heracles recounts his journey to the Garden of the Hesperides to steal the golden apples and slaying Ladon. See link