Charyon ferried the souls of the dead across the River Styx.
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Hades oversees the souls in the Underworld.
No the Greek underworld is not hell because it has a certain place where the souls of good people go where as hell is a place where unsaved bad souls go, although there is a spot in the underworld were bad souls do go.
psychopomp
Hades is the ruler of the underworld also known as Hades. Hades, the place, is known as where the dead people go when they die in Greek and Roman mythology.
He is the god of the underworld To watch over the underworld and to make sure that no souls escape.