The Greek god Apollo was the god that Delphi was dedicated to. Apollo killed a serpent Python there and the Greeks held the Pythian Games every four years to commemorate this.
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Apollo's Oracle was located in Delphi, so he became the patron in order to look after it.
There is no Greek God or Goddess of Teachers, officially, but Athena was the Goddess of knowledge and could be considered the patron Goddess of teachers AND students.
Athena the Greek goddess was patron of Athens, she was goddess of wise counsel, war, the defence of towns, heroic endeavour, weaving, pottery and other crafts.
usually the temple of a greek god or goddess was to sacrifice to that god or goddess on their holidays and to honor them if they were your patron god. The main temple of said god usually housed their acolyotes
Athena is considered the god of teaching because she is the goddess of wisdom thus making her The patron god of teaching.