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Caledonia probabaly. Which is what Scotland was origonally called after it was unified in 1000 odd. By unified i mean, when the different regions and people (such as the picts, the normans etc.) came together to form one nation.
The Sassanid Empire was centered in the country now known as Iran.
France
Greece joined what was then known as the European Economic Community in 1981. It is now known as the European Union.
Italy Mainly from Galileo's contributions I belive