I don't think there was a state with exactly 48 counties that joined the Union. West Virginia with 55 counties broke off from Virginia and joined the Union. 28 counties in Tennessee, mostly in the eastern part of the state supported the Union. Various counties in other Confederate states where plantations did not dominate the economy also supported the Union or at least felt opposed to secession.
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Delaware, Kentucky, Maryland, and Missouri were four slave states that did not secede from the Union. West Virginia, another slave state, seceded from Virginia and joined the Union during the Civil War. it was 4 that didn't secede from the union.
no it stayed in the union as a border state
On January 10, 1861, Florida delegates, who were meeting in Tallahassee, the state capital, voted to secede from the U.S. With that action, Florida became one of the original 6 states to secede from the U.S. and form the Confederacy. (A factoid from America's Library.)
No, it was not a state at the time, only a territory and thus couldn't sucede from the union.
Yes but when West Virginia was admitted to the Union, it was considered a "border state". West Virginia broke off from Virgina, and was admitted to the Union, as a slave state, in June 1863, and did not secede from the Union. West Virginia broke off from Virginia because there was heavy dispute amongst the counties, which became West Virginia and Virginia, regarding the issue of secession.