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Napalm is jellied gasoline. When used offensively, it will stick to what it hits and will evaporate less quickly if it does not immediately flame up (as it should).
Since the US could NOT use atomic weapons (and doctrine dictated no use of chemical/bio weapons); the US used every other weapon that it had at it's disposal. Another words, until someone said "it couldn't be used"; IT WAS USED! As far as napalm being used in warfare; it's a fire weapon...and fire has been part of warfare since the ancient Greeks used it before Christ (BC).
During World War II, the Luftwaffe, the German Air Force, dropped various types of bombs on their targets. These included high-explosive bombs, incendiary bombs, fragmentation bombs, and bunker buster bombs. Each type of bomb served a different purpose, whether it was to cause damage and destruction, start fires, or penetrate fortified structures.