It means to withdraw membership from an organization. ie: The south seceded from the union during the civil war.
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Seceed is the word for the formal withdraw of a membership from a union, usually a political or religious reference.
If you are referring to withdraw from the Union, the term is "secede".
When the Confederate States declared themselves an independent contry they withdrew from United States of America, They were no longer 'united'. The union of the states was broken because they were no longer one country. The term for this was secede.
South Carolina threatened to secede in 1833 with the Nullification Act.
secede
secede.