The members of the Triple Entente (Great Britain, France, Russia) were called the Allies.
The Triple Alliance (Germany, Austro-Hungary, Italy) changed its name to Central Powers because Italy entered the war on the side of the Allies in 1915.
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Prior to World War I, a Triple Alliance existed (mostly in secret) between Germany, the Austria-Hungary Empire, and Italy. Italy did not enter the war in support of her allies, however. By contrast, during the war, the "Triple Entente" of Britain, France, and Russia did hold together until the collapse of Russia in 1917.
Triple Entente, Triple Alliance and Neutrality were the 3 central powers in WW1
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The Triple Alliance
Both Germany and Italy were allies of Austria during World War I but Italy didn't like Austria very much. This alliance among Austria, Italy, and Germany was called the Triple Alliance.
The Triple Alliance was composed of France, Britain, and Russia.