In 1987
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Germany was the first country to use gas, chlorine in particular, in world war one. it was first used against British and French units in the first battle of Ypres.
April 1915 was the first time chlorine gas was fired off and gas masks were used.
Germany. They used Chlorine gas in the second battle of Ypres.
Gasses were invented well before World War 1. The Britons originally thought that gas was not a weapon but it was the french who through out the first gas grenade. Chlorine gas was first made by the Germans.
Germany was the first country to use poison gas