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Germany, Greece, most South American Countries, Algeria, Afghanistan, Austria, Belarus, Bangladesh, and many many more.
Most countries now a days are industrialized to some degree, though there are many that remain somewhat agrarian. Russia, America and Germany are all industrialized countries.
The closest city to an international border would depend on the specific border in question. For example, in the United States, the city of San Diego is one of the closest cities to the international border with Mexico. In Europe, the city of Strasbourg in France is close to the border with Germany. The proximity of a city to an international border can vary depending on the country and border in question.
There are 257 countries in the world.
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