Department of Foreign Affairs: Secretary of State Thomas Jefferson
Treasury Department: Secretary of the Treasury Alexander Hamilton
War Department: Secretary of War Henry Knox
Justice Department: Attorney General Edmund Randolph
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He divided the work of the Executive Branch into departments and used the head of each department as an advisor.
General Grant
Timothy Geithner is the Secretary of Treasury which means he is the head of the department
Shaun Donovan is the head of the HUD
An administrative head is the head of an administrative department. The exact duties will depend upon the organization they are with.