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George Washington was the first President of the United States, taking office in April of 1789. William McKinley was elected to a 2nd term in 1900 as the 25th President.
The first US Presidents who were father and son were John Adams and John Quincy Adams (the 2nd President and the 6th President). George H. W. Bush and George W. Bush are the second and most recent father-son pair that were US Presidents (the 41st and 43rd US Presidents).
No US presidents were named Nathaniel.
If you're asking whether any US Presidents were constitutionally ineligible to hold office, the answer is no.
There hasn't been any presidents from Rhode Island, yet.