I assume you are talking about the United States... the sequence goes like this:
President
Vice-President
Speaker of the House
President pro tempore of the Senate
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Next in line is the Vice President, followed by the Speaker of the House.
President Pro Tempore
The third person in line is the President Pro Tempore of the U.S. Senate, following the Vice President and Speaker of the House.
President pro tempore of the Senate.
No, if the President is removed, retires or dies the Vice President will become President. If the Vice President can't fill the office for some reason then next in line is the Speaker of the House of Representatives.