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There were two -- Lewis Cass and Jeremiah Black -- plus one who was an "acting" secretary, William Hunter. Lewis Cass of Michigan. For the last three months of Buchanan's term Cass was replaced by Jeremiah S Black of Pennsylvania.

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Lewis Cass was from 1857 to 1860, then Jeremiah S. Black was from 1860 to 1861

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Q: Who was President Buchanan's secretary of state?
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