All of us. It is the basic law of the land and sets the laws for all others. Without it there would not be a framework for goverment.
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The President of the United States is the Commander-in-Chief of the US military. Article II, Section 2 of the US Constitution.
George Washington was the first , since he was the first President. Article II, Section Two, Clause One of the US Constitution empowers the President of the US as the Commander in Chief. (Washington was also the commander-in-chief of the Colonial Army )
Bhimrao Ramji Ambedkar
There is no chief executive of the United States Constitution. If you are asking who is supposed to uphold the Constitution and make sure it is followed, that would be the President of the U.S. and the Congress (Senate and House of Representatives). I believe they all take oaths when they are sworn in to uphold it.
John James