Well, that is an interesting question. I would say Tenskwatawa.
The leader of US forces was William Henry Harrison, but the leader of the native American forces, Tecumseh, wasn't actually involved in the battle at all. His brother Tenskwatawa, a spiritual leader, was in charge while Tecumseh was out recruiting. He led a force to attack Harrison's forces, and was ultimately driven away, but Tecumseh rebuilt and continued to oppose the US, ultimately joining the British in the War of 1812.
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Tippecanoe
The battle took place on November 7, 1811 and lasted about 2 hours.
Tippecanoe was the nickname of William Henry Harrison. He received the nickname after a battle against native Americans near the Tippecanoe River when he was Governor of the Indiana Territory. His running mate in the 1840 presidential election was John Tyler.
The Battle of Tippecanoe occurred in the War of 1812; in which US was fighting with Britain. Also, native Americans who fought in the war mostly took Britain's side. They did this in hope of getting their land back, which was taken by the US in the development of going farther west.
William Henry Harrison