Achilles was raised and taught by Chiron, a centaur and son of Cronus/Kronos and Rhea.
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The goddess of Achilles is actually the "Mother" of Achilles and the answer is Thetis (The Mother of Achilles)
It was pure chance - no one knew about Achilles' weak spot except for himself, his mother, and possibly his mentor, Chiron.
Achilles , his heel
Both Herclues and Achilles were born half-god, Hercules by his father: Zeus, and Achilles by his mother: Thetis. Thetis further attempted to make Achilles invulnerable by dipping him in the Styx.
Hephaestus.