Rutherford B. Hayes during the Civil War. (I thought it was Washington, but he had only two.)
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Miraculously not. He had horses shot out from under him, and found bullet holes in his coat after battles, but was never actually shot or otherwise wounded.
The Battle of Lexington.
Ronald Reagan. He was shot by a homeless man trying to impress an actress that was there. He thought she was pretty and thought she would date him if he looked powerful. Instead, he went to imprisonment. I found this out at the Ronald Reagan Library in California.
Aaron Burr shot and killed Alexander in a duel. Dick Johnson supposedly killed Indian chief Tecumseh in battle. Dick Cheney accidentally wounded a hunting companion but not seriously. There may be others.
Lincoln